The DSpace digital repository system captures, stores, indexes, preserves, and distributes digital research material. http://dspace-roma3.caspur.it:80 2013-05-24T10:54:56Z 2013-05-24T10:54:56Z Vitaliano, Rosa Fratoddi, Ilaria Venditti, Iole Roviello, Giuseppina Battocchio, Chiara Polzonetti, Giovanni Russo, Maria Vittoria http://hdl.handle.net/2307/340 2011-12-22T13:34:34Z 2009-07-31T22:00:00Z

<Title>Self-Assembled Monolayers Based on Pd-Containing Organometallic Thiols:Preparation and Structural Characterization</Title> <Authors>Vitaliano, Rosa; Fratoddi, Ilaria; Venditti, Iole; Roviello, Giuseppina; Battocchio, Chiara; Polzonetti, Giovanni; Russo, Maria Vittoria</Authors> <Issue Date>2009-08</Issue Date> <Is part of>The Journal of phisical chemistry A</Is part of> <Volume>113</Volume> <Pages>14730–14740</Pages> <Abstract>Multilayers and self-assembled monolayers of on-purpose-preparedorganometallic thiolates, trans-[Pd(PBu3)(2)(SCOCH3)(2)], trans-[(C6H5CC)Pd(PBu3)(2)(SCOCH3)], and trans, trans-[(CH3COS)Pd(PBu3)(2)-(CC-C6H4-C6H4-C C)(PBu3)(2)Pd(SCOCH3)] Were deposited onto goldsurfaces. High-resolution X-ray photoelectron spectroscopy andnear-edge X-ray absorption fine structure measurements allowed us toassess the anchoring of the organometallic thiols onto gold substrates;the interaction occurring at the interface; and their molecularorientation oil the surface with tilt angles of about 30 degrees-40degrees, depending on. the investigated molecule. The molecule packingdensity/coverage was also assessed.</Abstract>

2009-07-31T22:00:00Z